課程大綱

課程資訊

課程名稱

有機金屬化學
Organometallic Chemistry

開課學期

107-2

授課對象

理學院化學所化學組

授課教師

江建文

課號

Chem5112

課程識別碼

223 U0950

班次

學分

3.0

全/半年

半年

必/選修

選修

上課時間

星期二6(13:20~14:10)星期四6,7(13:20~15:10)

上課地點

化217化217

備註

本課程中文授課,使用英文教科書。
限學士班三年級以上且限本系所學生(含輔系、雙修生)
總人數上限：60人

Ceiba 課程網頁

http://ceiba.ntu.edu.tw/1072Chem5112_

課程簡介影片

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課程大綱

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課程概述

We will start to introduce different classes of ligands. The process of ligand interacts with metal. Last section will be introduction of organic reactions involving organometallic compounds.

課程目標

A course to give students understand what is organometallic chemistry and its applications.

課程要求

Understanding the basic of organometallic chemistry

預期每週課後學習時數

Office Hours

另約時間備註： email lecturer at anytime and face to face conversation fixed by email.

指定閱讀

The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill

參考書目

The Organometallic Chemistry of the Transition Metals, 5th Ed.by R H Crabtree
Organometallics, 3rd Ed. by C Elschenbroich
Organotransition Metal Chemistry by A F Hill

評量方式
(僅供參考)

No.	項目	百分比	說明
1.	Midterm exam	30%	KV will be in charge
2.	Report	20%	KV will be in charge
3.	Final exam	50%	Professor Hiroshi Nakazawa will be in charge

課程進度

週次	日期	單元主題
第1週	2/19,2/21	By KV Introduction: What is organometallics? EAN rule and 18 electron rule
第2週	2/26,2/28	By KV Inorganic ligands • Carbonyl • Phosphines • Other related ligands 2/28 Public Holiday - No Class
第3週	3/05,3/07	By KV Alkyl, hydride and related monohapto ligands • Alkyls, aryls, vinyl, alkynyl, etc • Hydride Updated Syllabus Experiments and Techniques in Organometallic Chemistry
第4週	3/12,3/14	By KV Updated power point for lecture 3 Carbenes and carbynes • Carbenes • Carbynes Ligands employing p-electrons • Alkene, alkyne, diene and benzene • Metallocenes • Allyl, (cyclo)pentadienyl
第5週	3/19,3/21	By KV Organometallic Complexes Viewed from Molecular Orbital Theory
第6週	3/26,3/28	By KV Lab demonstration
第7週	4/02,4/04	Public Holidays- NO Class
第8週	4/09,4/11	By KV Organometallic Complexes Viewed from Molecular Orbital Theory
第9週	4/16,4/18	Mid Term 18/4
第10週	4/23,4/25	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第11週	4/30,5/02	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第12週	5/07,5/09	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第13週	5/14,5/16	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第14週	5/21,5/23	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第15週	5/28,5/30	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第16週	6/04,6/06	By Professor Hiroshi Nakazawa • Oxidative Addition Reaction • Reductive Elimination Reaction • CO insertion Reaction • Olefin Insertion Reaction and -hydride Abstraction • Catalytic Reaction Involving Organometallic Catalyst (Ziegler-Natta Reaction, Olefin Isomerization reaction, Hydroformylation Reaction) • Catalytic Reaction Involving Organometallic Catalyst (Wacker Process, Monsanto Process)
第17週	6/11,6/13	Final Exam 13/6